{"created":"2023-07-25T10:30:28.555664+00:00","id":9761,"links":{},"metadata":{"_buckets":{"deposit":"7aaf74be-40c2-4474-9e0a-469e58d67761"},"_deposit":{"created_by":4,"id":"9761","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"9761"},"status":"published"},"_oai":{"id":"oai:naist.repo.nii.ac.jp:00009761","sets":["49:50"]},"author_link":["28055","28056","28057","192","28058"],"item_7_biblio_info_9":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-05-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"20","bibliographicPageEnd":"5947","bibliographicPageStart":"5943","bibliographicVolumeNumber":"54","bibliographic_titles":[{"bibliographic_title":"Angewandte Chemie International Edition","bibliographic_titleLang":"en"}]}]},"item_7_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Directing the supramolecular polymerization towards a preferred type of organization is extremely important in the design of functional soft materials. Proposed herein is a simple methodology to tune the length and optical chirality of supramolecular polymers formed from a chiral bichromophoric binaphthalene by the control of enantiomeric excess (ee). The enantiopure compound gave thin fibers longer than a few microns, while the racemic mixture favored the formation of nanoparticles. The thermodynamic study unveils that the heterochiral assembly gets preference over the homochiral assembly. The stronger heterochiral binding over homochiral one terminated the elongation of fibrous assembly, thus leading to a control over the length of fibers in the nonracemic mixtures. The supramolecular polymerization driven by π?π interactions highlights the effect of the geometry of a twisted π-core on this self-sorting assembly.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_7_publisher_10":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-VCH Verlag","subitem_publisher_language":"en"}]},"item_7_relation_15":{"attribute_name":"PubMed番号","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"25802205","subitem_relation_type_select":"PMID"}}]},"item_7_relation_17":{"attribute_name":"出版者版DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201500292","subitem_relation_type_select":"DOI"}}]},"item_7_rights_18":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim","subitem_rights_language":"en"},{"subitem_rights":"This is the peer reviewed version of the following article: Angewandte Chemie International Edition: 2015 May;20(54);5943-5947, which has been published in final form at 10.1002/anie.201500292. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_7_source_id_12":{"attribute_name":"EISSN/PISSN","attribute_value_mlt":[{"subitem_source_identifier":"1521-3773","subitem_source_identifier_type":"ISSN"}]},"item_7_source_id_14":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11614189","subitem_source_identifier_type":"NCID"}]},"item_7_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kumar, Jatish","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"28055","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tsumatori, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"28056","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yuasa, Junpei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"28057","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kawai, Tsuyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"192","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40221197","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=40221197"}]},{"creatorNames":[{"creatorName":"Nakashima, Takuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"28058","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-03-06"}],"displaytype":"detail","filename":"201500292_main.pdf","filesize":[{"value":"511.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"fulltext","objectType":"fulltext","url":"https://naist.repo.nii.ac.jp/record/9761/files/201500292_main.pdf"},"version_id":"8cb197f1-d770-4796-8304-10ca69ee3ff1"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"chirality","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"luminescence","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"polarized spectroscopy","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"self-assembly","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"supramolecular chemistry","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Self-Discriminating Termination of Chiral Supramolecular Polymerization: Tuning the Length of Nanofibers","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Self-Discriminating Termination of Chiral Supramolecular Polymerization: Tuning the Length of Nanofibers","subitem_title_language":"en"}]},"item_type_id":"7","owner":"4","path":["50"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-09-11"},"publish_date":"2017-09-11","publish_status":"0","recid":"9761","relation_version_is_last":true,"title":["Self-Discriminating Termination of Chiral Supramolecular Polymerization: Tuning the Length of Nanofibers"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-11-29T09:08:56.846794+00:00"}