{"created":"2023-07-25T10:30:28.382407+00:00","id":9757,"links":{},"metadata":{"_buckets":{"deposit":"495072f8-69e8-47ef-8a80-a39ccbb7755b"},"_deposit":{"created_by":4,"id":"9757","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"9757"},"status":"published"},"_oai":{"id":"oai:naist.repo.nii.ac.jp:00009757","sets":["49:50"]},"author_link":["28022","28023","28024","278","293","28025","22","28026","5"],"item_7_biblio_info_9":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"01-03","bibliographicPageEnd":"478","bibliographicPageStart":"465","bibliographicVolumeNumber":"19","bibliographic_titles":[{"bibliographic_title":"Journal of Porphyrins and Phthalocyanines","bibliographic_titleLang":"en"}]}]},"item_7_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The copper(II), nickel(II), etc. complexes of 5,15-bis(trimethylsilylethynyl)tetrabenzoporphyrin (TMS-H2BP) and 5,15-bis(triisopropylsilylethynyl)tetrabenzoporphyrin (TIPS-H2BP) have been prepared from the corresponding bicycle[2.2.2]octadiene(BCOD)-fused precursors by the retro-Diels-Alder reaction. X-ray diffraction (XRD) analyses show that TMS-H2BP and its metal complexes of zinc(II) (TMS-ZnBP) and copper(II) (TMS-CuBP) adopt flat molecular conformations and form herringbone-type packing structures in the single crystalline state. TIPS-H2BP and the zinc(II) and copper(II) complexes (TIPS-ZnBP and TIPS-CuBP) are similar to the TMS derivatives in molecular conformation, but these TIPS derivatives form one-dimensional slipped-stack structures. The nickel complexes TMS-NiBP and TIPS-NiBP have U-shaped structures because of the small size of nickel(II) ion. Solution processed organic thin-film transistors of the benzoporphyrins were fabricated and TMS-H2BP showed the highest hole mobility of 0.11 cm2.V-1.s-1. Bulk heterojunction organic solar cells based on TMS- or TIPS-H2BP and their metal complexes as p-type and PC71BM as n-type materials were fabricated by solution process. Atomic force microscopy and thin-film XRD measurements indicated that the film crystallinities were increased by raising the annealing temperature over 180°C or by changing the substituents from triisopropylsilyl to trimethylsilyl. The best power-conversion efficiency (PCE) of 1.49% was achieved with TMS-ZnBP by annealing at 180°C with a moderate crystallinity and smooth surface.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_7_publisher_10":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"World Scientific Publishing","subitem_publisher_language":"en"}]},"item_7_relation_17":{"attribute_name":"出版者版DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1142/S1088424615500388","subitem_relation_type_select":"DOI"}}]},"item_7_rights_18":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright c 2015 World Scientific Publishing Company","subitem_rights_language":"en"},{"subitem_rights":"Electronic version of an article published as J. Porphyrins Phthalocyanines, 19, 01-03, 2015, 465-478, 10.1142/S1088424615500388, c copyright World Scientific Publishing Company, https://doi.org/10.1142/S1088424615500388","subitem_rights_language":"en"}]},"item_7_source_id_12":{"attribute_name":"EISSN/PISSN","attribute_value_mlt":[{"subitem_source_identifier":"1088-4246","subitem_source_identifier_type":"ISSN"}]},"item_7_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Takahashi, Kohtaro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"28022","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamada, Naoya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"28023","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kumagai, Daichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"28024","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kuzuhara, Daiki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"278","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"00583717","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=00583717"}]},{"creatorNames":[{"creatorName":"Suzuki, Mitsuharu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"293","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"20724959","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=20724959"}]},{"creatorNames":[{"creatorName":"Yamaguchi, Yuji","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"28025","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{}]}],"creatorNames":[{"creatorName":"Aratani, Naoki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"22","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60372562","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60372562"}]},{"creatorNames":[{"creatorName":"Nakayama, Ken-ichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"28026","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamada, Hiroko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"5","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"20372724","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=20372724"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-03-06"}],"displaytype":"detail","filename":"jpp2015,465.pdf","filesize":[{"value":"20.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"fulltext","objectType":"fulltext","url":"https://naist.repo.nii.ac.jp/record/9757/files/jpp2015,465.pdf"},"version_id":"1b778d7d-803f-44d0-86e4-c2c23e6d0c06"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"benzoporphyrin","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"metal complexes","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"crystal structure","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"organic solar cells","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Effect of alkyl substituents: 5,15-bis(trimethylsilylethynyl)- vs. 5,15-bis(triisopropylsilylethynyl)-tetrabenzoporphyrins and their metal complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Effect of alkyl substituents: 5,15-bis(trimethylsilylethynyl)- vs. 5,15-bis(triisopropylsilylethynyl)-tetrabenzoporphyrins and their metal complexes","subitem_title_language":"en"}]},"item_type_id":"7","owner":"4","path":["50"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-08-08"},"publish_date":"2017-08-08","publish_status":"0","recid":"9757","relation_version_is_last":true,"title":["Effect of alkyl substituents: 5,15-bis(trimethylsilylethynyl)- vs. 5,15-bis(triisopropylsilylethynyl)-tetrabenzoporphyrins and their metal complexes"],"weko_creator_id":"4","weko_shared_id":-1},"updated":"2023-11-29T09:08:46.538759+00:00"}