@article{oai:naist.repo.nii.ac.jp:00009750, author = {Yamashita, Masataka and Kuzuhara, Daiki and Aratani, Naoki and Yamada, Hiroko}, issue = {21}, journal = {Chemistry - A European Journal}, month = {Apr}, note = {A tetrathiafulvalene (TTF)-conjugated bistetracene was synthesized and characterized in the molecular electronic structures based on the spectroscopic measurements and the single-crystal X-ray diffraction analysis. UV/Vis absorption and electrochemical measurements of 5 revealed the considerable electronic communication between two tetracenedithiole units by through-bond and/or through-space interactions. The difference in the crystal-packing structures of 5, showing polymorphism, results in a variety of intermolecular electronic-coupling pattern. Of these, the π-stacking structure of 5 A gave a large transfer integral of HOMOs (97 meV), which value is beyond hexacene and rubrene, thus, quite beneficial to achieve the high hole mobility.}, pages = {6309--6314}, title = {Synthesis and Solid-State Structures of a Tetrathiafulvalene-Conjugated Bistetracene}, volume = {20}, year = {2014} }