| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2026-03-26 |
| 日付 |
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日付 |
2026-08-06 |
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日付タイプ |
Available |
| タイトル |
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タイトル |
Ultra-stretchable Transparent Hydrogels with Low Hydrophobic and Amphiphilic Monomers Using Asymmetric Crosslinker to Give Low Mechanical Hysteresis |
| 言語 |
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言語 |
eng |
| キーワード |
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主題Scheme |
Other |
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主題 |
copolymer |
| キーワード |
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主題Scheme |
Other |
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主題 |
hydrogel |
| キーワード |
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主題Scheme |
Other |
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主題 |
hydrophobicity |
| キーワード |
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主題Scheme |
Other |
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主題 |
N-vinylamide |
| キーワード |
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主題Scheme |
Other |
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主題 |
stretchable |
| 資源タイプ |
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資源タイプ |
journal article |
| アクセス権 |
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アクセス権 |
embargoed access |
| 著者 |
吉田, 裕安材
Maeno, Takanori
Kawatani, Ryo
Miyaji, Yumi
網代, 広治
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
Exploring a reasonable network design to develop highly stretchable hydrogels with over 1,000% extension is still a big challenge in the field of hydrogel chemistry and materials. Micellar copolymerization with hydrophobic monomers and surfactants/proteins is a well-studied approach to provide stretchable hydrogels with hydrophobic association domains as sacrificial bonds when subjected to large deformation, but some limitations, such as dose increase of such monomers and surfactant-free synthesis have not yet been well considered. In this study, we demonstrate a simple but powerful approach to produce transparent, ultra-stretchable hydrogels expressing more than 3,000% elongation by surfactant-free copolymerization of low hydrophobic monomer and amphiphilic monomer. We believe that this result offers wider availability of low hydrophobic groups in various water-containing polymer materials, including gels, micelles, etc. |
| 書誌情報 |
en : Chemistry - A European Journal
巻 31,
号 55,
ページ数 11,
発行日 2025-08-06
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| 出版者 |
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出版者 |
Wiley |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
1521-3765 |
| 出版者版DOI |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1002/chem.202500778 |
| 出版者版URI |
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関連タイプ |
isVersionOf |
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識別子タイプ |
URI |
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関連識別子 |
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.202500778 |
| 権利 |
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権利情報 |
© 2025 Wiley-VCH GmbH. This is the peer reviewed version of the following article: Yoshida Hiroaki, Maeno Takanori, Kawatani Ryo, Miyaji Yumi, Ajiro Hiroharu. 2025. Ultra-stretchable Transparent Hydrogels with Low Hydrophobic and Amphiphilic Monomers Using Asymmetric Crosslinker to Give Low Mechanical Hysteresis. Chemistry - A European Journal. 31(5), e00778, which has been published in final form at https://doi.org/10.1002/chem.202500778 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. 出版社許諾条件により、本文は2026年8月6日以降に公開 |
| 著者版フラグ |
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出版タイプ |
AM |
| 助成情報 |
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助成機関名 |
Japan Society for the Promotion of Science (JSPS) |
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研究課題番号 |
JP22H04547 |
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研究課題番号URI |
https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-22H04547/ |
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研究課題名 |
N-ビニルアミドに特徴的な水和挙動解析と化学結合型表面修飾による新規ゲル材料創出 |
| 助成情報 |
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助成機関名 |
Izumi Science and Technology Foundation |
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研究課題番号 |
2024-J-047 |