| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2026-03-12 |
| 日付 |
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|
日付 |
2026-09-05 |
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日付タイプ |
Available |
| タイトル |
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タイトル |
Investigation on regulated copolymer composition in free-radical flow polymerization through tube length variation |
| 言語 |
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|
言語 |
eng |
| キーワード |
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|
主題Scheme |
Other |
|
主題 |
Polymerization |
| キーワード |
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主題Scheme |
Other |
|
主題 |
Chemical reaction |
| キーワード |
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|
主題Scheme |
Other |
|
主題 |
Chemical composition |
| キーワード |
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主題Scheme |
Other |
|
主題 |
Molecular weight |
| 資源タイプ |
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資源タイプ |
journal article |
| アクセス権 |
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アクセス権 |
embargoed access |
| 著者 |
Nag, Aniruddha
Wakiuchi, Araki
高須賀, 聖五
Asano, Shigehito
Hashizume, Ryo
Hatanaka, Miho
宮尾, 知幸
Ohnishi, Yuya
松原, 崇充
安藤, 剛
Sugawara, Tetsunori
藤井, 幹也
網代, 広治
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| 抄録 |
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内容記述タイプ |
Abstract |
|
内容記述 |
This study focuses on optimizing free-radical copolymerization in a flow system, emphasizing control over monomer composition—a key factor in industrial applications that require homogeneous products and high conversion. Tubes of varying lengths (2.5 m, 5 m, 7.5 m, 10 m) were used to investigate time-dependent variables under random polymerization conditions. Using a method previously shown to achieve precise 50:50 copolymer compositions with styrene and methyl methacrylate, the same was applied in flow conditions. While copolymer composition remained stable, monomer conversion rates varied with tube length and molecular weights were comparable, demonstrating the process’s industrial relevance and tunability. |
| 書誌情報 |
en : MRS Communications
巻 15,
p. 1122-1128,
ページ数 7,
発行日 2025-09-05
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| 出版者 |
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出版者 |
Springer |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
2159-6867 |
| 出版者版DOI |
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関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
https://doi.org/10.1557/s43579-025-00813-x |
| 出版者版URI |
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|
関連タイプ |
isVersionOf |
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|
識別子タイプ |
URI |
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|
関連識別子 |
https://link.springer.com/article/10.1557/s43579-025-00813-x |
| 権利 |
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|
権利情報 |
Copyright © 2025, The Author(s), under exclusive licence to The Materials Research Society. This version of the article has been accepted for publication, after peer review (when applicable) and is subject to Springer Nature’s AM terms of use, but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections. The Version of Record is available online at: http://dx.doi.org/10.1557/s43579-025-00813-x. 出版社許諾条件により、本文は2026年9月5日以降に公開。 |
| 著者版フラグ |
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出版タイプ |
AM |
| 助成情報 |
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助成機関名 |
New Energy and Industrial Technology Development Organization (NEDO) |
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研究課題番号 |
JPNP14004 |
fulltext (1.5 MB)
