| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2025-12-04 |
| タイトル |
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タイトル |
Experimental and Theoretical Factors in CO2 Reduction on Pd-Based Electrocatalysts and their Applicability for Integration with Data Science and High-Throughput Experiments |
| 言語 |
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言語 |
eng |
| キーワード |
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主題Scheme |
Other |
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主題 |
density functional theory |
| キーワード |
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主題Scheme |
Other |
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主題 |
lectrochemical CO 2reductions |
| キーワード |
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主題Scheme |
Other |
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主題 |
intermetallic compounds |
| キーワード |
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主題Scheme |
Other |
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主題 |
Pd-based alloys |
| キーワード |
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主題Scheme |
Other |
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主題 |
solid solution |
| 資源タイプ |
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資源タイプ |
review article |
| アクセス権 |
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アクセス権 |
open access |
| 著者 |
高山, 大鑑
高須賀, 聖五
原嶋, 庸介
藤井, 幹也
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
This review showcases crucial factors in mechanisms of electrochemical CO2 reduction by taking Pd-based electrocatalysts (mainly, monometallic Pd and Pd-based alloy nanoparticles) as examples. There are dependencies of experimental conditions (e.g., applied potentials) and constituent elements of the electrocatalysts on the reduction products of electrochemical CO2 reduction. Moreover, Pd-based electrocatalysts have unique characteristics in electrochemical CO2 reduction: alteration in selectivities for CO and HCOOH formations by applied potentials, almost no overpotential for HCOOH formation, deactivation of their electrocatalyses by poisoning with CO formed through CO2 reduction, and in situ formation of palladium hydride. Here, we survey the characteristics of Pd-based electrocatalysts in terms of experimental and theoretical insights. Then, it is described that formation energies of intermediates estimated by density functional theory calculations are understandable factors to explain experimental performances of Pd-based electrocatalysts. Considering the estimated factors, this review exhibits a perspective of utilization of the factors to advance the research activity of electrochemical CO2 reduction to its new horizon by using data science and high-throughput experiments. |
| 書誌情報 |
en : ChemElectroChem
巻 12,
号 20,
p. 1-21,
ページ数 21,
発行日 2025-09-04
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| 出版者 |
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出版者 |
Weliy-VCH |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
2196-0216 |
| 出版者版DOI |
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関連タイプ |
isIdenticalTo |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1002/celc.202500151 |
| 出版者版URI |
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関連タイプ |
isIdenticalTo |
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識別子タイプ |
URI |
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関連識別子 |
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/celc.202500151 |
| 権利 |
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権利情報Resource |
https://creativecommons.org/licenses/by/4.0/ |
|
権利情報 |
© 2025 The Author(s). ChemElectroChem published by Wiley-VCH GmbH. Thisis an open access article under the terms of the Creative Commons AttributionLicense, which permits use, distribution and reproduction in any medium,provided the original work is properly cited. |
| 著者版フラグ |
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出版タイプ |
VoR |
fulltext (6.5 MB)
