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Investigation of the mechanical properties and degradation of ester-free poly(trimethylene carbonate) derivatives bearing various bulky aromatic groups
http://hdl.handle.net/10061/0002001073
http://hdl.handle.net/10061/0002001073fc78711f-3765-41f2-adb4-67810b48df2c
| 名前 / ファイル | ライセンス | アクション |
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fulltext (1.6 MB)
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| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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| 公開日 | 2025-07-30 | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Investigation of the mechanical properties and degradation of ester-free poly(trimethylene carbonate) derivatives bearing various bulky aromatic groups | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| キーワード | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Biochemistry | |||||||||||||
| キーワード | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | Environmental chemistry | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ | journal article | |||||||||||||
| アクセス権 | ||||||||||||||
| アクセス権 | open access | |||||||||||||
| 著者 |
Miyake, Rikyu
× Miyake, Rikyu
× 網代, 広治
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| 抄録 | ||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||
| 内容記述 | Ester-free trimethylene carbonate derivatives bearing bulky aromatic groups were designed and synthesized, including those with one or two benzyl groups, diphenylmethyl groups, and triphenylmethyl groups. The polymerization reactions of these monomers were investigated with several initiators. The mechanical properties of the polymers were determined with compressive tests, resulting in approximately 0.3$2009MPa at most. The degradation behaviors were also evaluated in lipase solutions and aqueous 0.01$2009M NaOH for several weeks, which revealed that the substituents impeded degradation in most cases. The degradation processes were slow, and they were analyzed with weight loss, SEM, SEC, TGA, and DSC studies. | |||||||||||||
| 書誌情報 |
en : Polymer Journal 巻 56, 号 4, p. 319-333, ページ数 15, 発行日 2024-04-01 |
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| 出版者 | ||||||||||||||
| 出版者 | Springer Nature | |||||||||||||
| ISSN | ||||||||||||||
| 収録物識別子タイプ | EISSN | |||||||||||||
| 収録物識別子 | 1349-0540 | |||||||||||||
| 出版者版DOI | ||||||||||||||
| 関連タイプ | isVersionOf | |||||||||||||
| 識別子タイプ | DOI | |||||||||||||
| 関連識別子 | https://doi.org/10.1038/s41428-023-00848-8 | |||||||||||||
| 出版者版URI | ||||||||||||||
| 関連タイプ | isVersionOf | |||||||||||||
| 識別子タイプ | URI | |||||||||||||
| 関連識別子 | https://www.nature.com/articles/s41428-023-00848-8 | |||||||||||||
| 権利 | ||||||||||||||
| 権利情報 | Copyright $00A9 2023, The Author(s), under exclusive licence to The Society of Polymer Science, Japan. | |||||||||||||
| 著者版フラグ | ||||||||||||||
| 出版タイプ | AM | |||||||||||||
| 助成情報 | ||||||||||||||
| 助成機関名 | Japan Society for the Promotion of Science (JSPS) | |||||||||||||
| 研究課題番号 | JP22H04547 | |||||||||||||
| 研究課題番号URI | https://kaken.nii.ac.jp/grant/KAKENHI-PUBLICLY-22H04547/ | |||||||||||||
| 研究課題名 | N-ビニルアミドに特徴的な水和挙動解析と化学結合型表面修飾による新規ゲル材料創出 | |||||||||||||
| 助成情報 | ||||||||||||||
| 助成機関名 | Japan Society for the Promotion of Science (JSPS) | |||||||||||||
| 研究課題番号 | JP20H02799 | |||||||||||||
| 研究課題番号URI | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20H02799/ | |||||||||||||
| 研究課題名 | 汎用五大高分子の代替となるエステルフリー型生分解性高分子の設計と合成 | |||||||||||||
| 助成情報 | ||||||||||||||
| 助成機関名 | Japan Society for the Promotion of Science (JSPS) | |||||||||||||
| 研究課題番号 | JP19KK0277 | |||||||||||||
| 研究課題番号URI | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19KK0277/ | |||||||||||||
| 研究課題名 | 動脈若返りのために複数薬剤徐放と分解をタイムプログラムした高分子材料創製 | |||||||||||||
| 助成情報 | ||||||||||||||
| 助成機関名 | The Mazda Foundation | |||||||||||||
| 研究課題番号 | 21KK-134 | |||||||||||||
