| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2025-07-03 |
| 日付 |
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日付 |
2026-01-02 |
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日付タイプ |
Available |
| タイトル |
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タイトル |
Synthesis and Spectroscopic Properties of Diarylethene-Subporphyrinoid Hybrids |
| 言語 |
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言語 |
eng |
| キーワード |
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|
主題Scheme |
Other |
|
主題 |
Subphthalocyanine |
| キーワード |
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主題Scheme |
Other |
|
主題 |
Porphyrinoids |
| キーワード |
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主題Scheme |
Other |
|
主題 |
Diarylethene |
| キーワード |
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主題Scheme |
Other |
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主題 |
Photochromism |
| キーワード |
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主題Scheme |
Other |
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主題 |
DFT calculation |
| 資源タイプ |
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資源タイプ |
journal article |
| アクセス権 |
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アクセス権 |
embargoed access |
| 著者 |
Muto, Taichi
山田, 美穂子
Tamiya, Nanari
Takagi, Akuto
Mizutani, Tadashi
Bourissou, Didier
Rapenne, Gwenael
河合, 壯
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
Two novel diarylethene-fused subporphyrinoids were prepared and characterized. A mono diarylethene derivative was obtained via a statistical condensation reaction with 2$2005eq. of 1,2-dicyanobenzene and 1$2005eq. of thiophene-disubstituted butenedinitrile. The symmetric triply diarylethene-fused subporphyrazine was synthesized via a cyclotrimerization reaction of the thiophene-disubstituted butenedinitrile derivative. These compounds were characterized by NMR spectroscopy and high-resolution mass spectrometry. The spectroscopic properties have been measured in hexane and in chloroform. The mono diarylethene-fused-type compound showed photochromism at 580$2005nm and >700$2005nm wavelength, accompanied by degradation. According to DFT calculations, photoreactivity likely depends on the contribution of aromatic feature of pyrrole ring bonded to two thiophene rings. |
| 書誌情報 |
en : ChemPhysChem
巻 26,
号 1,
発行日 2025-01-02
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| 出版者 |
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出版者 |
Wiley |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
1439-7641 |
| 出版者版DOI |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1002/cphc.202400615 |
| 出版者版URI |
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関連タイプ |
isVersionOf |
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識別子タイプ |
URI |
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関連識別子 |
https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cphc.202400615 |
| 権利 |
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権利情報 |
$00A9 2024 Wiley-VCH GmbH. This is the peer reviewed version of the following article:Taichi Muto, Nanari Tamiya, Akuto Takagi, Tadashi Mizutani, Didier Bourissou, Gwenael Rapenne, Mihoko Yamada, Tsuyoshi Kawai.2024. Synthesis and spectroscopic properties of diarylethene-subporphirinoid hybrids. ChemPhysChem. 26(1), e202400615, which has been published in final form at https://doi.org/10.1002/cphc.202400615. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. 出版社許諾条件により、本文は2026年1月2日以降に公開。 |
| 著者版フラグ |
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出版タイプ |
AM |
| 助成情報 |
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助成機関名 |
Japan Society for the Promotion of Science (JSPS) |
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研究課題番号 |
JP23H04876 |
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研究課題名 |
メゾ光機能科学 |
| 助成情報 |
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助成機関名 |
Japan Society for the Promotion of Science (JSPS) |
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研究課題番号 |
JP22H05134 |
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研究課題名 |
超螺旋光とキラル秩序の相互作用による励起子コヒーレント制御 |
| 助成情報 |
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助成機関名 |
Japan Society for the Promotion of Science (JSPS) |
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|
研究課題番号 |
JP24K08361 |
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研究課題名 |
湾曲状芳香族配位子を有する希土類錯体構築と歪み構造に基づく光機能制御 |
| 助成情報 |
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助成機関名 |
Japan Society for the Promotion of Science (JSPS) |
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研究課題番号 |
JP22H00325 |
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研究課題名 |
Motor-based molecular machines in action: Winch & Gears |
| 助成情報 |
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助成機関名 |
Japan Society for the Promotion of Science (JSPS) |
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研究課題番号 |
JP22H02052 |
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研究課題名 |
超高感度分子ドシメーターを目指した分子超増幅系の開拓 |
fulltext (1.2 MB)
