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RAFT polymerisation of N-vinylformamide and the corresponding double hydrophilic block copolymers
http://hdl.handle.net/10061/0002000735
http://hdl.handle.net/10061/000200073518fc46de-a606-4512-b588-d7dffa13810c
| 名前 / ファイル | ライセンス | アクション |
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fulltext (1.2 MB)
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| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||||||
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| 公開日 | 2025-01-14 | |||||||||||||||||||||
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| タイトル | RAFT polymerisation of N-vinylformamide and the corresponding double hydrophilic block copolymers | |||||||||||||||||||||
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| 言語 | eng | |||||||||||||||||||||
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| 資源タイプ | journal article | |||||||||||||||||||||
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| アクセス権 | open access | |||||||||||||||||||||
| 著者 |
Dupre--Demorsy, Alexis
× Dupre--Demorsy, Alexis
× Kurowska, Izabela
× Balayssac, St$00E9phane
× Hennetier, Marie
× Ric, Audrey
× Bourdon, Val$00E9rie
× 安藤, 剛× 網代, 広治× Coutelier, Olivier
× Destarac, Mathias
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| 内容記述タイプ | Abstract | |||||||||||||||||||||
| 内容記述 | Reversible addition$2013fragmentation chain transfer (RAFT) homopolymerisation of N-vinylformamide (NVF) is reported for the first time. Reactions were conducted in DMSO at 35 °C using a xanthate RAFT agent. PNVFs of predetermined molar masses up to Mn $223C 80$2006000 g mol$22121 and low dispersities (<1.4) were synthesized. Excellent chain-end fidelity was confirmed by ESI-TOF mass spectrometry. A series of double hydrophilic block copolymers comprising a PNVF segment were successfully synthesized and characterized via asymmetric flow field flow fractionation (AF4) and 1H DOSY-NMR techniques. Finally, poly(N-vinylcaprolactam)-b-poly(N-vinylformamide) (PVCL-b-PNVF) was hydrolysed into the original dual responsive poly(N-vinylcaprolactam)-b-poly(N-vinylamine) (PVCL-b-PVAm), thus revealing the strong potential of this RAFT approach to develop PVAm-based complex architectures. | |||||||||||||||||||||
| 書誌情報 |
en : Polymer Chemistry 巻 13, 号 44, p. 6229-6237, 発行日 2022-10-17 |
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| 出版者 | Royal Society of Chemistry | |||||||||||||||||||||
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| 収録物識別子タイプ | EISSN | |||||||||||||||||||||
| 収録物識別子 | 1759-9962 | |||||||||||||||||||||
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| 関連タイプ | isVersionOf | |||||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||||||
| 関連識別子 | https://doi.org/10.1039/D2PY00925K | |||||||||||||||||||||
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| 関連タイプ | isVersionOf | |||||||||||||||||||||
| 識別子タイプ | URI | |||||||||||||||||||||
| 関連識別子 | https://pubs.rsc.org/en/content/articlelanding/2022/py/d2py00925k | |||||||||||||||||||||
| 権利 | ||||||||||||||||||||||
| 権利情報 | $00A9 The Royal Society of Chemistry 2022 | |||||||||||||||||||||
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| 出版タイプ | AM | |||||||||||||||||||||
