| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2025-01-07 |
| タイトル |
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タイトル |
Composition Regulation by Flow Copolymerization of Methyl Methacrylate and Glycidyl Methacrylate with Free Radical Method |
| 言語 |
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言語 |
eng |
| キーワード |
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|
主題Scheme |
Other |
|
主題 |
flow systems |
| キーワード |
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|
主題Scheme |
Other |
|
主題 |
glycidyl methacrylate |
| キーワード |
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|
主題Scheme |
Other |
|
主題 |
radical polymerizations |
| 資源タイプ |
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資源タイプ |
journal article |
| アクセス権 |
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アクセス権 |
open access |
| 著者 |
Wakiuchi, Araki
Takasuka, Shogo
Asano, Shigehito
Hashizume, Ryo
Nag, Aniruddha
Hatanaka, Miho
宮尾, 知幸
Ohnishi, Yuya
松原, 崇充
安藤, 剛
Sugawara, Tetsunori
藤井, 幹也
網代, 広治
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| 抄録 |
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内容記述タイプ |
Abstract |
|
内容記述 |
It is important to match the feeding ratio of comonomers to the composition ratio in the resulting copolymers as closely as possible in industrial production, where the goal is often to produce more a homogeneous composition in copolymers. In this study, a flow copolymerization system with a conventionally initiated free radical method, together with randomly selected polymerization conditions is investigated. It is succeeded in achieving a closer match between the composition ratio and feeding ratio than previously reported in the copolymerization of styrene with methyl methacrylate and of glycidyl methacrylate with methyl methacrylate, which will widen the range of applications, by precisely controlling the mixing and heating in a flow polymerization apparatus. This is confirmed by the fact that the estimated values of reactivity ratios, r1 and r2, which are used in the reaction kinetics of copolymerization, are close to 1. |
| 書誌情報 |
en : Macromolecular Materials and Engineering
巻 308,
号 6,
発行日 2023-01-22
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| 出版者 |
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出版者 |
Wiley |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
1439-2054 |
| 出版者版DOI |
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関連タイプ |
isReplacedBy |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
https://doi.org/10.1002/mame.202200626 |
| 出版者版URI |
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関連タイプ |
isReplacedBy |
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|
識別子タイプ |
URI |
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|
関連識別子 |
https://onlinelibrary.wiley.com/doi/10.1002/mame.202200626 |
| 権利 |
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|
権利情報Resource |
https://creativecommons.org/licenses/by/4.0/ |
|
権利情報 |
$00A9 2022 The Authors. Macromolecular Materials and Engineeringpublished by Wiley-VCH GmbH. This is an open access article under theterms of the Creative Commons Attribution License, which permits use,distribution and reproduction in any medium, provided the original workis properly cited. |
| 著者版フラグ |
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|
出版タイプ |
NA |
