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Bottom-Up Synthesis of Multiply Fused PdII Anthriporphyrinoids
http://hdl.handle.net/10061/0002000514
http://hdl.handle.net/10061/0002000514a73c2549-abd9-4c70-8e71-2ae3a9726969
| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||||
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| 公開日 | 2024-08-06 | |||||||||||||||||||
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| タイトル | Bottom-Up Synthesis of Multiply Fused PdII Anthriporphyrinoids | |||||||||||||||||||
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| 言語 | eng | |||||||||||||||||||
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| 資源タイプ | journal article | |||||||||||||||||||
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| アクセス権 | open access | |||||||||||||||||||
| 著者 |
Ge, Xinrun
× Ge, Xinrun
× Rao, Yutao
× Xu, Ling
× Zhou, Mingbo
× Kurosaki, Ryo
× 荒谷, 直樹× Osuka, Atsuhiro
× Song, Jianxin
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| 内容記述タイプ | Abstract | |||||||||||||||||||
| 内容記述 | Anthriporphyrinoid and its dimeric homologues were synthesized by Suzuki$2013Miyaura coupling and subsequent oxidation. Both porphyrinoids were smoothly converted to their PdII complexes and were further decorated by Suzuki$2013Miyaura coupling with thiophene derivatives and subsequent oxidative fusion reaction to provide multiply fused compounds. Most PdII anthriporphyrinoids have been structurally well characterized to be planar for monomeric and helically twisted for dimeric species. The dimeric anthriporphyrinoids show paratropic ring currents due to their global antiaromatic networks, the extent of which increases with an increase of conjugated network. Multiply fused dimeric anthriporphyrinoids show helical structures, fully reversible six redox potentials, small HOMO$2013LUMO gaps, and absorption tails reaching in the near-infrared region, suggesting the high potential of this approach to explore molecular graphene. Optical separations of the dimeric helical species were accomplished, and racemization barrier heights were determined. | |||||||||||||||||||
| 書誌情報 |
en : ACS Central Science 巻 8, 号 12, p. 1627-1632, 発行日 2022-12-08 |
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| 出版者 | American Chemical Society | |||||||||||||||||||
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| 収録物識別子タイプ | EISSN | |||||||||||||||||||
| 収録物識別子 | 2374-7951 | |||||||||||||||||||
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| 関連タイプ | isReferencedBy | |||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||||
| 関連識別子 | https://doi.org/10.1021/acscentsci.2c01218 | |||||||||||||||||||
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| 関連タイプ | isReplacedBy | |||||||||||||||||||
| 識別子タイプ | URI | |||||||||||||||||||
| 関連識別子 | https://pubs.acs.org/doi/full/10.1021/acscentsci.2c01218 | |||||||||||||||||||
| 権利 | ||||||||||||||||||||
| 権利情報Resource | https://creativecommons.org/licenses/by/4.0/ | |||||||||||||||||||
| 権利情報 | Copyright $00A9 2022 The Authors. This publication is licensed under CC-BY 4.0 . | |||||||||||||||||||
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| 出版タイプ | NA | |||||||||||||||||||
