| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2024-08-05 |
| タイトル |
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タイトル |
Synthesis of polyacene by using a metal$2013organic framework |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ |
journal article |
| アクセス権 |
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アクセス権 |
open access |
| 著者 |
Kitao, Takashi
Miura, Takumi
Nakayama, Ryo
Tsutsui, Yusuke
Chan, Yee Seng
Hayashi, Hironobu
山田, 容子
Seki, Shu
Hitosugi, Taro
Uemura, Takashi
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
The acene series, an important class of linearly polycyclic aromatic hydrocarbons, are of interest owing to their unique physicochemical features. With an increase in the number of fused benzene rings, acenes display an evolution of electronic structure and properties. Thus, efforts have been devoted to the synthesis of longer acenes, with dodecacene being the longest acene (12 fused benzene rings) reported to date. However, the formation of polymeric acenes with numerous benzene rings, namely polyacene, has yet to be realized. Herein, we present a methodology for the synthesis of polyacene mediated by a metal$2013organic framework. Nanoconfined synthesis of precursor polymers in the channels of the metal$2013organic framework and the subsequent dehydro-aromatization reaction produced polyacene that was overwhelmingly longer than the previously reported acenes. The scalable synthesis of polyacene allowed us to unveil the stability and electronic properties of polyacene, paving the way for their widespread applications in optoelectronic and magnetic devices. |
| 書誌情報 |
en : Nature Synthesis
巻 2,
号 9,
p. 848-854,
発行日 2023-05-04
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| 出版者 |
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出版者 |
Nature Research |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
2731-0582 |
| 出版者版DOI |
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関連タイプ |
isReplacedBy |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1038/s44160-023-00310-w |
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関連タイプ |
isReplacedBy |
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識別子タイプ |
URI |
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関連識別子 |
https://www.nature.com/articles/s44160-023-00310-w |
| 権利 |
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権利情報Resource |
http://creativecommons.org/licenses/by/4.0/ |
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権利情報 |
$00A9 The Author(s) 2023 This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
| 著者版フラグ |
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出版タイプ |
NA |
