| アイテムタイプ |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2024-06-12 |
| タイトル |
|
|
タイトル |
Tailor-Made Poly(vinylamine) via Purple LED-Activated RAFT Polymerization of N-vinylformamide |
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
PI-RAFT |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
poly(N-vinylformamide) |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
poly(vinylamine) |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
xanthate |
| 資源タイプ |
|
|
資源タイプ |
journal article |
| アクセス権 |
|
|
アクセス権 |
open access |
| 著者 |
Kurowska, Izabela
Dupre$2013Demorsy, Alexis
Balayssac, St$00E9phane
Hennetier, Marie
Ric, Audrey
Bourdon, Val$00E9rie
安藤, 剛
網代, 広治
Coutelier, Olivier
Destarac, Mathias
|
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
Photo-iniferter reversible addition-fragmentation chain transfer (PI-RAFT) polymerization of N-vinylformamide (NVF) is demonstrated by using purple light. PNVFs with predetermined molar masses and narrow molar mass distributions are obtained. High RAFT chain-end fidelity is confirmed by matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) and electrospray-ionization time-of-flight mass spectrometry (ESI-TOF-MS), and chain extension experiment. To demonstrate the potential of this approach, an original poly(N-vinylpyrrolidone)-b-poly(N-vinylformamide) (PVP-b-PNVF) diblock copolymer is synthesized and characterized by aqueous size-exclusion chromatography (SEC), asymmetric flow field-flow fractionation (A4F), and 1H diffusion-ordered spectroscopy nuclear magnetic resonance (1H DOSY NMR). Finally, selective hydrolysis of PNVF block to corresponding pH-responsive poly(N-vinylpyrrolidone)-b-poly(N-vinylformamide) (PVP-b-PVAm) is performed. |
| 書誌情報 |
en : Macromolecular Rapid Communications
巻 44,
号 4,
発行日 2022-11-28
|
| 出版者 |
|
|
出版者 |
Macromolecular Rapid Communications |
| ISSN |
|
|
収録物識別子タイプ |
EISSN |
|
収録物識別子 |
1521-3927 |
| 出版者版DOI |
|
|
関連タイプ |
isReplacedBy |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
https://doi.org/10.1002/marc.202200729 |
| 出版者版URI |
|
|
関連タイプ |
isReplacedBy |
|
|
識別子タイプ |
URI |
|
|
関連識別子 |
https://onlinelibrary.wiley.com/doi/10.1002/marc.202200729 |
| 権利 |
|
|
権利情報Resource |
http://creativecommons.org/licenses/by/4.0/ |
|
権利情報 |
$00A9 2022 The Authors. Macromolecular Rapid Communications published by Wiley-VCH GmbH. This is an open access article under the terms ofthe Creative Commons Attribution License, which permits use,distribution and reproduction in any medium, provided the original workis properly cited. |
| 著者版フラグ |
|
|
出版タイプ |
NA |
